4.6 Article

A comparison of H+-restacked nanosheets and nanoscrolls derived from K4Nb6O17 for visible-light degradation of dyes

Journal

JOURNAL OF ENERGY CHEMISTRY
Volume 23, Issue 2, Pages 136-144

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/S2095-4956(14)60128-5

Keywords

K4Nb6O17; nanosheets; nanoscrolls; photodegradation; dye

Funding

  1. National Natural Science Foundation of China [21073084, 20773065]
  2. Natural Science Foundation of Jiangsu Province [BK2011438]
  3. 973 Project [2009CB623504]
  4. Specialized Research Fund for the Doctoral Program of Higher Education [20130091110010]
  5. Modern Analysis Center of Nanjing University

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H+-restacked nanosheets and nanoscrolls peeled from K4Nb6O17 display different structures and surface characters. The two restacked samples with increased surface areas have an amazing visible-light response for the photodegradation of dyes, which is superior to commercial TiO2 (P25) and Nb2O5. By comparison, H+/nanosheets have a relatively faster photodegradation rate originated from large and smooth basal plane. The work reveals that dye adsorbed on the unfolded nanosheets can effectively harvest sunlight. Due to facile preparation, low-cost and high photocatalytic efficiency, H+/nanosheets and H+/nanoscrolls might be used for the visible light-driven degradation of organic dyes as a substitute for TiO2 in industry.

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