Journal
IEEE JOURNAL OF PHOTOVOLTAICS
Volume 3, Issue 4, Pages 1250-1258Publisher
IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC
DOI: 10.1109/JPHOTOV.2013.2279116
Keywords
Crucible; iron; silicon; simulation; vertical gradient freeze (VGF)
Funding
- German Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU) [0325270G]
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The aim of this paper is to analyze the limiting role of crucible and coating impurities on material quality of multicrystalline silicon. Both solid body diffusion and diffusion into the silicon melt are considered in this study. Two ingots of size G1 have been analyzed. One of them was crystallized in a standard crucible, whereas the other was crystallized in a quartz crucible of very high purity. Focus is put on iron and cobalt as examples of typical impurity species. Iron was found in large concentrations in standard crucibles, and cobalt was proven to be a suitable marker impurity that is mainly found in the coating. Inductively coupled plasma mass spectroscopy data are exploited for the determination of impurity concentrations in crucible, coating, and within the crystal. With higher sensitivity for low concentration, PL imaging is applied for carrier lifetime and interstitial iron concentration measurements. The different findings are compared with modeling results of iron and cobalt in-diffusion by Sentaurus Process. The analysis of silicon wafers before and after gettering steps enable a quantification of impurity-limiting cell efficiency potential. Conclusions about the role of impurities from coated crucibles in large-scale crystallization are deduced.
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