Journal
APPLIED SCIENCES-BASEL
Volume 5, Issue 3, Pages 380-401Publisher
MDPI
DOI: 10.3390/app5030380
Keywords
homogeneous catalysis; hydration reactions; platinum; amides; nitriles; organic synthesis
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Funding
- Ministerio de Economia y Competitividad (MINECO) of Spain [CTQ2013-40591-P, CTQ2014-51912-REDC]
- Gobierno del Principado de Asturias [GRUPIN14-006]
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The air-stable hydride-platinum(II) complex [PtH{(PMe2O)(2)H}(PMe2OH)], reported by Parkins and co-workers in 1995, is the most versatile catalyst currently available for the hydration of C N bonds. It features remarkable activity under relatively mild conditions and exceptionally high functional group compatibility, facts that have allowed the implementation of this complex in the synthesis of a large number of structurally complex, biologically active molecules and natural products. In this contribution, synthetic applications of the Parkins catalyst are reviewed.
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