Journal
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Volume 71, Issue -, Pages 298-+Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S205322961500474X
Keywords
gold(III) complex; methimazole; crystal structure; S-donor ligands; metal-organic compound
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Funding
- Armstrong State University
- American Chemical Society Petroleum Research Fund (PRF) [53848-UNI3]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1229354] Funding Source: National Science Foundation
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The cationic pseudo-square-planar complex tetrakis(1-methyl-2,3-dihydro-1H-imidazole-2-thione-kappa S)gold(III) trichloride sesquihydrate, [Au(C4H6N2S)(4)]Cl-3 center dot 1.5H(2)O, was isolated as dark-red crystals from the reaction of chloroauric acid trihydrate (HAuCl4 center dot 3H(2)O) with four equivalents of methimazole in methanol. The Au-III atoms reside at the corners of the unit cell on an inversion center and are bound by the S atoms of four methimazole ligands in a planar arrangement, with S-Au-S bond angles of approximately 90 degrees.
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