Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 3, Issue 3, Pages 273-276Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201300236
Keywords
alkenes; copper; oxidative coupling; oxindoles; trifluoromethylation
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Funding
- 973 Program [2012CB725302]
- National Natural Science Foundation of China [21390400, 21025206, 21272180, 21302148]
- Research Fund for the Doctoral Program of Higher Education of China [20120141130002]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
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A copper-catalyzed radical oxidative trifluoromethylation and arylation of electron-withdrawing alkenes has been developed, in which economical sodium trifluoromethanesulfinate is used as the CF3 source. A preliminary kinetic investigation indicated that the generation of CF3 radicals under the mild conditions might be a facile process.
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