4.5 Article

Copper-Catalyzed Trifluoromethylation-Initiated Radical Oxidative Annulation toward Oxindoles

Journal

ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 3, Issue 3, Pages 273-276

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201300236

Keywords

alkenes; copper; oxidative coupling; oxindoles; trifluoromethylation

Funding

  1. 973 Program [2012CB725302]
  2. National Natural Science Foundation of China [21390400, 21025206, 21272180, 21302148]
  3. Research Fund for the Doctoral Program of Higher Education of China [20120141130002]
  4. Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]

Ask authors/readers for more resources

A copper-catalyzed radical oxidative trifluoromethylation and arylation of electron-withdrawing alkenes has been developed, in which economical sodium trifluoromethanesulfinate is used as the CF3 source. A preliminary kinetic investigation indicated that the generation of CF3 radicals under the mild conditions might be a facile process.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.5
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available