Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 11, Issue -, Pages -Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.11.27
Keywords
DMSO; electrosynthesis; epoxides; halohydrins; halogen cations
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Funding
- Taiyo Nippon Sanso Corporation
- Grants-in-Aid for Scientific Research [25410200] Funding Source: KAKEN
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beta-Haloalkoxysulfonium ions generated by the reaction of electrogenerated Br+ and I+ ions stabilized by dimethyl sulfoxide (DMSO) reacted with sodium hydroxide and sodium methoxide to give the corresponding halohydrins and epoxides, respectively, whereas the treatment with triethylamine gave alpha-halocarbonyl compounds.
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