Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 6, Issue 11, Pages 14554-14560Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.8b03180
Keywords
Metal-organic frameworks; Green synthesis; Water
Categories
Funding
- Spanish MINECO [PN MAT2015-65354-C2-1-R]
- Catalan AGAUR [2014 SGR 80]
- ERC, under EU-FP7 [ERC-Co 615954]
- EU Horizon 2020 research and innovation programme PRODIA [685727]
- CERCA Programme/Generalitat de Catalunya
- Spanish MINECO through the Severo Ochoa Centres of Excellence Programme [SEV-2013-0295]
Ask authors/readers for more resources
Demand continues for environmentally sound, high-yielding processes for the large-scale production of metal-organic frameworks (MOFs). Here we describe the use of metal acetylacetonate complexes as an alternative source of metals for the aqueous synthesis of MOFs. We have synthesized several carboxylate-based Zr(IV)-(UiO-66-NH2, Zr-fumarate, UiO-66-(OH)(2), UiO-66-COOH and UiO-66-(COOH)(2)), Fe(III)-(MIL-88A) and Al(III)-(CAU-10) porous MOFs from their corresponding metal acetylacetonates in good yields (typically >85%) and, in some cases, at room temperature.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
