Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 11, Issue -, Pages 1985-1990Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.11.214
Keywords
addition; green method; phosphine oxides; regioselectivity; vinyl sulfides
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Funding
- Russian Federation [NSh-156.2014.3]
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Secondary phosphine oxides react with vinyl sulfides (both alkyl- and aryl-substituted sulfides) under aerobic and solvent-free conditions (80 degrees C, air, 7-30 h) to afford 1-hydroxy-2-(organosulfanyl)ethyl(diorganyl)phosphine oxides in 70-93% yields.
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