Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 11, Issue -, Pages 1944-1949Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.11.210
Keywords
catalysis; cyclopropanation; indole; quinoline; Rh(II); ring expansion
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In this letter, we report a novel synthesis of ethyl quinoline-3-carboxylates from reactions between a series of indoles and halodiazoacetates. The formation of the quinoline structure is probably the result of a cyclopropanation at the 2- and 3-positions of the indole followed by ring-opening of the cyclopropane and elimination of H-X.
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