4.1 Article

Recent changes in methane mixing ratio and its C-13 content observed in the southwest Pacific region

Journal

JOURNAL OF INTEGRATIVE ENVIRONMENTAL SCIENCES
Volume 7, Issue -, Pages 109-117

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/19438151003621441

Keywords

methane; carbon-13; atmospheric composition

Funding

  1. New Zealand Foundation for Research, Science and Technology [C01X0703, C01X0406]
  2. Antarctica New Zealand with the Arrival Heights air sampling program

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After nearly a decade without growth in atmospheric methane, there are indications of renewed growth from 2007. Reports of this renewal portray it as global in extent, and due wholly or largely to growth in emissions. Surface methane mixing ratios and constituent delta C-13 values have been measured approximately twice monthly at Baring Head, New Zealand (41 degrees S, 175 degrees E) since 1989. Surface mixing ratios have been measured continuously at Lauder, New Zealand (45 degrees S, 170 degrees E) since 2007. Also at Lauder, tropospheric-mean mole fractions of methane have been retrieved from ground-based near-infrared solar spectra since 2004. These mixing ratio datasets are consistent with growth rates of about 7.5 and 4.9 ppb year(-1) during 2007 and 2008. We consider the possible origins of this growth based on their imprint on delta C-13 values.

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