4.5 Article

Facile Synthesis of Hierarchical Magnesium Silicate Hollow Nanofibers Assembled by Nanosheets as an Efficient Adsorbent

Journal

CHEMPLUSCHEM
Volume 80, Issue 3, Pages 544-548

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.201402293

Keywords

adsorption; hydrothermal synthesis; magnesium; nanostructures; silicates

Funding

  1. National Natural Science Foundation of China [21473027]
  2. Research Fund for the Doctoral Program of Higher Education of China [20120043110005]
  3. project development plan of science and technology of Jilin Province [20140101110JC]
  4. Opening Fund of State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry
  5. Chinese Academy of Sciences
  6. Opening Fund of State Key Laboratory of Inorganic Synthesis and Preparative Chemistry of Jilin University

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Magnesium silicate double-walled hollow nanofibers (MSHNFs) with a hierarchical nanostructure have been successfully fabricated by combining the electrospinning technique with a hydrothermal method. The as-prepared MSHNFs are composed of numerous ultrathin nanosheets with a thickness of approximately 10nm and have a high specific surface area (632.2m(2)g(-1)) and large pore volume (0.92cm(3)g(-1)). The MSHNFs exhibit high adsorption capacity and excellent stability in a purification test with organic molecules and a solution of heavy-metal ions. Moreover, the MSHNFs can be easily separated from solution by gravitational sedimentation owing to their unique structure.

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