Journal
CHEMPLUSCHEM
Volume 79, Issue 3, Pages 439-446Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.201300375
Keywords
conducting materials; electrochemistry; exfoliation; graphene; thin films
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Funding
- European Science Foundation (ESF) under the EUROCORES Program EuroGRAPHENE (GOSPEL)
- Operative Program FESR of Regione Emilia-Romagna-Attivita [I.1.1.]
- EC Marie-Curie ITN-GENIUS [PITN-GA-2010-264694]
- FET project UPGRADE [309056]
- Graphene Flagship [GA-604391]
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A facile and efficient method based on electrochemistry for the production of graphene-based materials for electronics is demonstrated. Uncharged acetonitrile molecules are intercalated in graphite by electrochemical treatment, owing to the synergic action of perchlorate ions dissolved in acetonitrile. Then, acetonitrile molecules are decomposed with microwave irradiation, which causes gas production and rapid graphite exfoliation, with an increase in the graphite volume of up to 600%. Upon further processing and purification, highly dispersible nanosheets are obtained that can be processed into thin layers by roll-to-roll transfer or into thicker electrodes with excellent capacitance stability upon extensive charging/discharging cycles. The good exfoliation yield (>50% of monolayers), minimal oxidation damage and good electrochemical stability of the nanosheets obtained were confirmed by scanning force and electron microscopy, as well as Raman spectroscopy and galvanostatic analyses.
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