Journal
CHEMPLUSCHEM
Volume 77, Issue 2, Pages 106-112Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.201100021
Keywords
amines; catalysis; Heck reactions; metal-organic frameworks; nanoparticles; palladium
Categories
Funding
- 973 Program [2011CB932504, 2012CB821705]
- NSFC [21003128, 20901078, 91022007]
- Fujian Key Laboratory of Nanomaterials [2006L2005]
- CAS
Ask authors/readers for more resources
Well-dispersed palladium nanoparticles (Pd NPs) supported on amine-functionalized, mixed-linker metal-organic frameworks (MIXMOFs) based on MIL-53(Al) were prepared by using the ion-exchange method. Pd NPs were characterized by powder X-ray diffraction (XRD), N-2 adsorption, transmission electron microscopy (TEM), inductively coupled plasma atomic emission spectroscopy (ICP-AES), and X-ray photoelectron spectroscopy (XPS). The mean diameter of Pd NPs is approximately 3.2 nm. It was found that the Pd NPs supported on amine-functionalized MIXMOFs are stable at high temperature. The Pd NPs exhibit efficient catalytic activity for Heck reaction and can be easily recovered and reused.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available