Journal
ACS MACRO LETTERS
Volume 3, Issue 9, Pages 948-952Publisher
AMER CHEMICAL SOC
DOI: 10.1021/mz500446z
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Funding
- TherMAT, Future Pioneering Projects of the Ministry of Economy, Trade and Industry, Japan
- MEXT, Japan [25888025]
- Grants-in-Aid for Scientific Research [25888025] Funding Source: KAKEN
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We reported general methods for studying the thermoelectric properties of a polymer film in both the in-plane and through-plane directions. The bench-mark PEDOT/PSS films have highly anisotropic carrier transport properties and thermal conductivity. The anisotropic carrier transport properties can be explained by the lamellar structure of the PEDOT/PSS films where the PEDOT nanocrystals could be isolated by the insulating PSS in the through-plane direction. The anisotropic thermal conductivity was mainly attributed to the lattice contribution from PSS because the polymer chain is oriented along the substrate.
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