Journal
ACS MACRO LETTERS
Volume 3, Issue 3, Pages 229-232Publisher
AMER CHEMICAL SOC
DOI: 10.1021/mz400649w
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Funding
- ACS-PRF [51026-ND10]
- NSF [CHE-1305773]
- WCU Program through the NRF of Korea - Ministry of Education, Science and Technology [R31-10013]
- NRF for the National Creative Research Initiative Center for Intelligent Hybrids [2010-0018290]
- Korean Ministry of Education, Science, and Technology through Institute of Basic Science (IBS) Program
- NIST [70NANB12H164]
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Sulfur-rich copolymers based on poly(sulfur-random-1,3-diisopropenylbenzene) (poly(S-r-DIB)) were synthesized via inverse vulcanization to create cathode materials for lithium sulfur battery applications. These materials exhibit enhanced capacity retention (1005 mAh/g at 100 cycles) and battery lifetimes over 500 cycles at a C/10 rate. These poly(S-r-DIB) copolymers represent a new class of polymeric electrode materials that exhibit one of the highest charge capacities reported, particularly after extended charge discharge cycling in Li-S batteries.
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