Journal
ACS MACRO LETTERS
Volume 3, Issue 8, Pages 773-777Publisher
AMER CHEMICAL SOC
DOI: 10.1021/mz500252f
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Funding
- National Science Foundation [DMR-1006659]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1006659] Funding Source: National Science Foundation
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The impact of spherical nanoparticIes (NPs) on the segmental dynamics of polymer melts is investigated. The addition of NPs broadens the segmental dynamics with effects of both particle size and loading. Interfacial bound layer thickness is calculated by the difference in magnitude of the segmental dynamics of pure polymer and nanocomposites. These theoretical models suggest that the bound layer thickness in the case of strongly adsorbing polymer matrices may increase with particle size.
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