Journal
ACS MACRO LETTERS
Volume 3, Issue 5, Pages 491-495Publisher
AMER CHEMICAL SOC
DOI: 10.1021/mz5001724
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Funding
- University of Warwick
- China Scholarship Council
- Innovative Uses for Advanced Materials in the Modern World (AM2)
- Advantage West Midlands (AWM)
- European Regional Development Fund (ERDF)
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A chemically unprotected mannose-containing acrylate (ManA) monomer was synthesized and polymerized by Cu(0)-mediated radical polymerization in water (SET-LRP). One-pot block copolymerization was achieved upon addition of a solution of N-isopropylacrylamide (NIPAm) or diethylene glycol ethyl ether acrylate (DEGEEA) forming thermoresponsive double hydrophilic diblock glycopolymers which revealed self-assembly properties in aqueous solution forming well-defined, sugar-decorated nanoparticles.
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