Journal
ACS MACRO LETTERS
Volume 1, Issue 8, Pages 1086-1089Publisher
AMER CHEMICAL SOC
DOI: 10.1021/mz300312e
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Funding
- National Basic Research Program of China (973 Program) [2012CB821503]
- National Natural Science Foundation of China [50930003]
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Polymer blends with dynamic asymmetry have attracted much interest recently. In this study, we report a more typical case where the dynamically asymmetric system is highly immiscible we find that there is a transient network growth and phase inversion for the slow minor component The network structure shows a hierarchical growth behavior, which is the result of competition between a slow relaxation-controlled concentration growth an local scale and a fast hydrodynamic growth on large scale: When phase separation couples with a subsequent crystallization, the interfacial boundary may assist lateral crystallization and irregular spherulites would grow epitaxially around the amorphous :component-morphological control in material processing.
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