Journal
ACS MACRO LETTERS
Volume 1, Issue 12, Pages 1383-1387Publisher
AMER CHEMICAL SOC
DOI: 10.1021/mz300535r
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- Abu Dhabi-Minnesota Institute for Research Excellence (ADMIRE)
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A variety of multisubstituted cyclooctenes were prepared and employed as monomers for ring-opening metathesis polymerization using the Grubbs second or third generation catalysts. The resulting polymers were characterized by NMR spectroscopy, size exclusion chromatography, and differential scanning calorimetry. Monomers possessing a substituent at the 3-position afforded highly regio- and stereoregular polyalkenamers, from which the corresponding sequence-specific vinyl quaterpolymers were obtained upon hydrogenation. Simultaneous control of tacticity was also demonstrated by employing monomers with defined stereochemistry.
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