Journal
ACS MACRO LETTERS
Volume 1, Issue 6, Pages 656-659Publisher
AMER CHEMICAL SOC
DOI: 10.1021/mz300210w
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Funding
- Iketani Science and Technology Foundation
- [23750172]
- Grants-in-Aid for Scientific Research [23750172] Funding Source: KAKEN
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The electro-click reaction of azide-functionalized poly(3,4-ethylenedioxythiophene) (PEDOT-N-3) and a terminal alkyne was investigated using electrogenerated Cu(I) species on a bipolar electrode in a gradient manner. The introduction of a perfluoroalkyl group derived from the alkyne moiety onto the PEDOT surface only at the cathodic part of the bipolar electrode was successfully characterized by X-ray analyses and the surface properties of the modified film were studied. The spectroscopic analysis of the rhodamine-functionalized PEDOT prepared similarly in a gradient manner was also performed with a UV-vis spectrophotometer.
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