Journal
ACS MACRO LETTERS
Volume 1, Issue 9, Pages 1108-1112Publisher
AMER CHEMICAL SOC
DOI: 10.1021/mz3002808
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Funding
- Japan Society for the Promotion of Science (JSPS), KAKENHI [22550137]
- Fundamental Research fund of AIST
- Grants-in-Aid for Scientific Research [22550137] Funding Source: KAKEN
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We synthesized gel-forming polyelectrolytes having N,N'-(trans-cyclohexane-1,4-diyl)dibenzamide linkages, with chloride, bis(trifluoromethanesulfonyl)amide, bis(fluorosulfonyl)amide, or tetrafluoroborate anions that could gelatinize a variety of ionic liquids at very low concentrations. The temperatures at which these ionogels transitioned into isotropic fluids were greater than 100 degrees C even at concentrations as low as 5 g/L. In addition, the ionogels exhibited high mechanical strength without a significant loss in their ionic conductivities, along with the rapid recovery.
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