Journal
ACS MACRO LETTERS
Volume 1, Issue 1, Pages 190-193Publisher
AMER CHEMICAL SOC
DOI: 10.1021/mz200076c
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Funding
- National Natural Science Foundation of China [20902031, 50973037]
- Fundamental Research Funds for the Central Universities (HUST) [Q2009029, 2011TS148]
- Wuhan ChenGuang Program [201150431118]
- National Basic Research Program [2011CB932501]
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A novel kind of star triptycene-based microporous polymer (STPs) was synthesized efficiently from trihalotriptycenes by nickel(0)-catalyzed Ullmann cross-coupling reactions. STPs display a BET surface area of 1305 m(2) g(-1) and 1990 m(2) g(-1), and, reversibly adsorb 1.60 and 1.93 wt % H-2 at 1.0 bar/77 K, 16.15 and 18.20 wt % CO2 at 1.0 bar/273 K for STP-I and STP-II, respectively.
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