Journal
ACS MACRO LETTERS
Volume 1, Issue 1, Pages 92-95Publisher
AMER CHEMICAL SOC
DOI: 10.1021/mz200087g
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Funding
- UHA
- CNRS
- UPMC
- U.S. National Science Foundation [CHE-0645998]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0956921] Funding Source: National Science Foundation
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Rate constants for important elementary reactions of 2,4-dimethyl-1,2,4-triazol-3-ylidene borane (1) and its derived boryl radical have been measured in the presence and absence of water. Reactions including H-abstraction by tBuO(center dot), and onward reactions of the derived radical with methyl acrylate (addition), iodopropane (halogen abstraction), and an iodonium salt (oxidation) are unaffected by the presence of a high concentration (1.5 M) of water. Extending these results, borane (1) has been found to be an efficient new co-initiator for the visible light photopolymerization of monomers in the presence of both air and water.
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