Journal
CHEMELECTROCHEM
Volume 3, Issue 1, Pages 152-157Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201500342
Keywords
catholytes; energy storage; lithium-sulfur batteries; membranes; shuttles
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Funding
- RIKEN
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Shuttling of soluble polysulfide species within electrodes is one of the most challenging issues in lithium-sulfur (Li-S) batteries. The resulting deposition of polysulfide species reduces the conductivity of the metallic Li electrode and the quantity of active material. Here, we demonstrate pronounced suppression of polysulfide shuttle using a sulfide-impermeable glass-ceramic membrane, which is employed as separator between the positive and negative electrodes. As a result, highly stable Li-S electrochemistry occurs in the sulfur-dissolving tetrahydrofuran catholyte solution, which provides good capacity retention and Coulombic efficiency for cycling. This demonstration holds promise for practical next-generation batteries with marked reversibility and the possibility to increase the energy density when equipped with a catholyte flow-through mode.
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