Journal
CATALYSTS
Volume 5, Issue 2, Pages 871-904Publisher
MDPI
DOI: 10.3390/catal5020871
Keywords
reaction kinetics; thermodynamic consistency; nickel; steam reforming; dry reforming; partial oxidation
Categories
Funding
- German Federal Ministry of Economics and Technology [FKZ 0327856A]
- BASF
- Linde AG
- hte AG
- Technische Universitat Munchen
- Universitat Leipzig
- Steinbeis GmbH & Co. KG fur Technologietransfer [STZ 240 Reaktive Stromung]
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An experimental and kinetic modeling study on the Ni-catalyzed conversion of methane under oxidative and reforming conditions is presented. The numerical model is based on a surface reaction mechanism consisting of 52 elementary-step like reactions with 14 surface and six gas-phase species. Reactions for the conversion of methane with oxygen, steam, and CO2 as well as methanation, water-gas shift reaction and carbon formation via Boudouard reaction are included. The mechanism is implemented in a one-dimensional flow field description of a fixed bed reactor. The model is evaluated by comparison of numerical simulations with data derived from isothermal experiments in a flow reactor over a powdered nickel-based catalyst using varying inlet gas compositions and operating temperatures. Furthermore, the influence of hydrogen and water as co-feed on methane dry reforming with CO2 is also investigated.
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