Journal
CATALYSTS
Volume 5, Issue 2, Pages 595-605Publisher
MDPI
DOI: 10.3390/catal5020595
Keywords
phase transfer catalysis; styrylisoxazoles; Michael initiated ring closing reactions
Categories
Funding
- Science Foundation Ireland (SFI)
- Irish Research Council for Science and Engineering (IRCSET)
- Fondazione con il Sud
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Heavily substituted cyclopropane esters were prepared in high yields, complete diastereoselection and average (up to 58%) enantioselectivity. The reaction described herein entailed reacting 4-nitro-5-bromostyrylisoxazoles, a class of powerful Michael acceptors with malonate esters under the catalysis of 5 mol% of a chincona derived phase-transfer catalyst.
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