4.7 Article

Fabricating of high-performance functional graphene fibers for micro-capacitive energy storage

Journal

SCIENTIFIC REPORTS
Volume 6, Issue -, Pages -

Publisher

NATURE PUBLISHING GROUP
DOI: 10.1038/srep29534

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Funding

  1. Shenzhen Science and Technology Research Grant [JCYJ20150629144612861]
  2. Shenzhen Key Laboratory of Organic Optoelectromagnetic Functional Materials of Shenzhen Science and Technology Plan [ZDSYS20140509094114164]
  3. Guangdong Talents Project
  4. NSFC [51373075]
  5. Nanjing University of Posts and Telecommunications basic research program [NY 212002]

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Although graphene is a typical two dimensional materials, it has converted to multi-dimensional materials with many unique properties. As an example, the one dimensional graphene fiber is fabricated by utilizing ionic liquid as coagulation and functional diamines as cross-linkers to connect graphene oxide layers. The fibers show excellent mechanical properties and superior electrical performance. The tensile strength of the resultant fibers reaches similar to 729 MPa after a super high temperature thermal annealing treatment at 2800 degrees C. Additionally, quasi-solid-state flexible micro-capacitors are fabricated with promising result on energy storage. The device show a specific volumetric capacity as high as similar to 225 F/cm(3) (measured at 103.5 mA cm(-3) in a three-electrode cell), as well as a long cycle life of 2000 times. The initial results indicate that these fibers will be a good candidate to replace energy storage devices for miniaturized portable electronic applications.

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