Journal
SCIENTIFIC REPORTS
Volume 4, Issue -, Pages -Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/srep03923
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Funding
- 973 program [2012CB821705, 2011CB932504]
- NSFC [91222105, 21203196, 21221001]
- NSF of Fujian Province [2011J06005]
- CAS [XDA07070200]
- NSF [DMR-0846958]
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As an integral part of a porous framework and uniformly distributed throughout the internal pore space, the high density of the exposed B-H bond in zeolite-like porous BIF-20 (BIF = Boron Imidazolate Framework) is shown here to effectively produce nanoparticles within its confined pore space. Small noble-metal nanoparticles (Ag or Au) are directly synthesized into its pores without the need for any external reducing agent or photochemical reactions, and the resulting Ag@BIF-20 (or Au@BIF-20) samples show high catalytic activities for the reduction of 4-nitrophenol.
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