4.7 Article

Polyoxometalate-based Supramolecular Gel

Journal

SCIENTIFIC REPORTS
Volume 3, Issue -, Pages -

Publisher

NATURE PUBLISHING GROUP
DOI: 10.1038/srep01833

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Funding

  1. NSFC [91127040, 20971078, 21221062]
  2. State Key Project of Fundamental Research for Nanoscience and Nanotechnology [2011CB932402]

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Self-assemblyings of surfactant-encapsulated Wells-Dawson polyoxometalates (SEPs) nanobuilding blocks in butanone and esters yielded supramolecular gels showing thermo and photo responsive properties. The gels can be further polymerized if unsaturated esters were used and subsequently electrospinned into nanowires and non-woven mats. The as-prepared non-woven mats have a Young's modulus as high as 542.55 MPa. It is believed that this supramolecular gel is a good platform for polyoxometalates processing.

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