Journal
RSC ADVANCES
Volume 4, Issue 77, Pages 40985-40993Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra05336b
Keywords
-
Categories
Funding
- National Basic Research Program of China (973 program) [2011CB935903]
- National Natural Science Foundation of China [21233004, 21021002]
Ask authors/readers for more resources
A Na2MnPO4F/C nanocomposite material is successfully synthesized via spray drying, followed by a high-temperature sintering method. It is shown that the highly phase-pure Na2MnPO4F with symmetry of the P2(1)/n space group is uniformly embedded in the carbon networks, which play a key role in building up a highly efficient, electron-flow channel and elevating the electronic conductivity of the nanocomposites. The electrochemical measurements show that the initial discharge capacity of Na2MnPO4F reaches up to 140 and 178 mA h g(-1) at 30 degrees C and 55 degrees C, respectively. Furthermore, the capacity still maintains 135 mA h g(-1) after 20 cycles at 55 degrees C. The Na+ diffusion coefficient in Na2MnPO4F is calculated at about 10(-17) cm(2) s(-1) by the GITT method. The impressive cycling performance of the material is ascribed to the good structural reversibility and stability of Na2MnPO4F, which are confirmed by the ex situ XRD measurements during the first cycle and after 30 cycles.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available