Journal
RSC ADVANCES
Volume 4, Issue 21, Pages 10968-10974Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra45288c
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Funding
- Natural Science Foundation of China [51172086, 51272081]
- Natural Science Foundation of Educational Committee of Anhui Province [KJ2013B241]
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Novel composite BiPO4/BiVO4 photocatalysts with different amounts of BiPO4 were synthesized by a simple one-pot hydrothermal method at pH 0.5. The obtained photocatalysts were systematically characterized using X-ray powder diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), X-ray photoelectron spectroscopy (XPS) and UV-vis diffuse reflectance spectroscopy (DRS). The photocatalytic activities of BiPO4/BiVO4 were evaluated by the degradation of methylene blue (MB), methyl orange (MO) and rhodamine B (RhB) under visible light (lambda > 400 nm). The results showed that all of the BiPO4/BiVO4 composites exhibited much higher photocatalytic activities than pure BiVO4 and BiPO4. Among the composites, 10% BiPO4/BiVO4 could degrade 92.1% MB after 5 h illumination and possessed the best photocatalytic activity. Meanwhile, the k value of 10% BiPO4/BiVO4 was 0.503 h(-1), which was twice that of pure BiVO4. The enhanced photocatalytic activity could be mainly ascribed to the suitable BiPO4/BiVO4 heterojunction interface which could effectively promote the separation of photoinduced electron-hole pairs. Moreover, the radical scavengers experiments demonstrated that O-center dot(2)- and h(+) were the main reactive species for MB degradation under visible light.
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