Journal
RSC ADVANCES
Volume 4, Issue 12, Pages 6173-6214Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra46996d
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Funding
- National Natural Science Foundation of China [21025209, 21121062, 21302209]
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The area of direct asymmetric functionalization of inert C-H bonds has attracted considerable attention in recent years. To realize this type of challenging but promising transformations, a lot of strategies have emerged including asymmetric C-H bond insertion by metal carbenoids or analogs, cross dehydrogenative coupling, [1,5]-hydride transfer, C-H bond functionalization involving a transient metal-carbon species and other miscellaneous methods. This review is intended to summarize and discuss the most recent developments (contributions mainly after 2009) within this area.
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