4.6 Article

CoMoO4 center dot 0.9H(2)O nanorods grown on reduced graphene oxide as advanced electrochemical pseudocapacitor materials

Journal

RSC ADVANCES
Volume 4, Issue 65, Pages 34307-34314

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra04827j

Keywords

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Funding

  1. National Natural Science Foundation of China [21171035, 51302035]
  2. Key Grant Project of Chinese Ministry of Education [313015]
  3. PhD Programs Foundation of the Ministry of Education of China [20110075110008, 20130075120001]
  4. National 863 Program of China [2013AA031903]
  5. Science and Technology Commission of Shanghai Municipality [13ZR1451200]
  6. Fundamental Research Funds for the Central Universities
  7. Program Innovative Research Team in University [IRT1221]
  8. Shanghai Leading Academic Discipline Project [B603]
  9. Program of Introducing Talents of Discipline to Universities [111-2-04]

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In this work, one-dimensional CoMoO4 center dot 0.9H(2)O nanorods grown on reduced graphene oxide hybrid composites (CoMoO4 center dot 0.9H(2)O-rGO) with good electrochemical properties have been synthesized by a simple and environmentally friendly hydrothermal synthesis procedure. The conductive graphene not only improves the electron conductivity of the overall electrode but also provides strong synergistic effects with Faradaic pseudo-capacitance (CoMoO4 center dot 0.9H(2)O). Meanwhile, rGO can act as a buffer for the volume change, which can provide an assurance for better cycling performance of the CoMoO4 center dot 0.9H(2)O-rGO hybrid composites. An exceptionally high specific capacitance of 802.2 F g(-1) at a current density of 1 A g(-1) and good cycle stability with capacitance retention of similar to 86.3% after 5000 cycles is obtained for the CoMoO4 center dot 0.9H(2)O-rGO composites. The remarkable electrochemical performance can make the CoMoO4 center dot 0.9H(2)O-rGO composites one of the most competitive electrode materials for electrochemical energy storage.

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