4.6 Article

Reversible piezofluorochromic nature and mechanism of aggregation-induced emission-active compounds based on simple modification

Journal

RSC ADVANCES
Volume 4, Issue 47, Pages 24649-24652

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra03042g

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Funding

  1. Program for New Century Excellent Talents in University (China)
  2. Doctoral Program Foundation of the Ministry of Education of China [20113401110004]
  3. National Natural Science Foundation of China [21271003, 21271004, 51372003]
  4. Ministry of Education
  5. Natural Science Foundation of Education Committee of Anhui Province [KJ2012A024]
  6. 211 Project of Anhui University
  7. Higher Education Revitalization Plan Talent Project

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Simple modification of triphenylamine generates four luminophores with aggregation-induced emission characteristics. Three of them can be smartly switched in fluorescence emissions by various external stimuli such as grinding, annealing and solvent-fuming, which may be attributed to the transformation from the crystalline state to the amorphous state and vice versa.

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