Journal
RSC ADVANCES
Volume 4, Issue 88, Pages 47593-47604Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra07622b
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Funding
- Department of Science and Technology (DST)
- Council of Scientific and Industrial Research (CSIR), New Delhi, India
- UGC, New Delhi
- CSIR, New Delhi, India
- UGC, New Delhi, India
- DST-SERB
- Department of Chemistry, University of Kalyani under PURSE, FIST and SAP programme.
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A nitrogen rich porous covalent imine network material (CIN-1) has been successfully employed for grafting silver nanoparticles (Ag NPs). The Ag NPs grafted CIN-1, Ag-CIN-1 has been characterized by elemental analysis, powder X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), UV-vis diffuse reflectance spectroscopy (DRS), thermogravimetric analysis (TGA) and EPR spectroscopic studies. Ag-CIN-1 acts as a truly heterogeneous catalyst in the hydration of nitriles to amides and the A(3) coupling reactions between the alkyne, amine and aldehyde to produce propargylamines by using water as a green solvent.
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