Journal
RSC ADVANCES
Volume 4, Issue 88, Pages 47389-47395Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra10031j
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Funding
- NRF - Korea government (MSIP) [2013R1A2A2A01067717]
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This paper reports on a fabrication method to manufacture cylindrically multi-channeled hollow carbon nanofibers (mcHCNFs). Polyacrylonitrile nanofibers with cylindrical multi-cores of poly(styrene-co-acrylontitrile) (SAN) were first electrospun using a specific nozzle and subsequently heat-treated, leaving vacant or silicon (Si)-encapsulated mcHCNFs. The latter was obtained by dispersing Si nanoparticles in the SAN solution. Investigations into the morphologies, microstructures, and material compositions of the resulting mcHCNFs demonstrated that Si-encapsulated multi-channels were formed in a controlled, uniform manner. The multi-channel effects were evaluated by characterizing the anodic properties of Si-encapsulated mcHCNFs using galvanostatic charge-discharge tests. More contact between the Si nanoparticles and the carbon shell in the Si-encapsulated mcHCNFs brought about improved discharge capacity and capacity retention.
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