4.6 Article

Surface Enhanced Raman Spectroscopy Using a Single Mode Nanophotonic-Plasmonic Platform

Journal

ACS PHOTONICS
Volume 3, Issue 1, Pages 102-108

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsphotonics.5b00487

Keywords

surface enhanced raman spectroscopy; single mode waveguide; photonic integrated circuits; plasmonic modeling

Funding

  1. ERC Grant InSpectra
  2. Bijzonder Onderzoeksfonds (BOF) fellowship of Ghent University

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We demonstrate the generation of Surface Enhanced Raman Spectroscopy (SERS) signals from integrated bowtie antennas, excited and collected by the fundamental TE mode of a single mode silicon nitride waveguide. Due to the integrated nature of this particular single mode SERS probe one can rigorously quantify the complete enhancement process. The Stokes power, generated by a 4-nitrothiophenol-coated antenna and collected into the fundamental TE mode, exhibits an 8 X 10(6) enhancement compared to the free space Raman scattering of a 4-nitrothiophenol molecule. Furthermore, we present an analytical model which identifies the relevant design parameters and fi SERS-platform. An excellent correspondence is obtained between the theoretically predicted and absolute Raman power. This work paves the way toward a new class of fully integrated lab-on-a-chip mode SERS probe can be combined with other photonic, fluidic, or biological functionalities.

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