4.6 Article

Polymer Distributed Bragg Reflectors for Vapor Sensing

Journal

ACS PHOTONICS
Volume 2, Issue 4, Pages 537-543

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ph500461w

Keywords

1D photonic crystals; polymer DBR; ZnO nanoparticles; optical nanocomposites; photonic crystal sensors

Funding

  1. Cariplo Foundation Project PHOENICS [2009-2461]
  2. Italian Ministry of University and Scientific and Technological Research [2010XLLNM3]
  3. Nanyang Technological University [M4080538]
  4. Singapore Ministry of Education [MOE2013-T2-044, MOE2011-T3-1-005]

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We establish a new strategy to achieve fast and responsive hybrid distributed Bragg reflectors for environmental vapor sensing. We fabricated easily processable zinc oxide-polystyrene nanocomposites to grow high quality multilayers with large gas permeability and dielectric contrast, which enable fast and sensitive detection of vapor analytes. Multilayers fabricated by simple spin-coating of the nanocomposite and cellulose acetate show a 10-fold enhancement of the optical response to toluene exposure compared to reference distributed Bragg reflectors built with bare. polystyrene.

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