Journal
RSC ADVANCES
Volume 4, Issue 81, Pages 42991-42995Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra07531e
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Funding
- National Basic Research Program of China [2013CB632404]
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Insoluble Prussian blue (IPB), Fe-4[Fe(CN)(6)](3), is synthesized at room temperature and found to achieve a relatively high storage capacity of 146 mA h g(-1) (at a 20 mA g(-1) rate) as the cathode material for Na-ion batteries with high potential plateaus. XRD, SEM and TEM are employed to characterize the morphology and microstructure of the as-synthesized IPB. First-principles calculation is introduced to study the electrochemical mechanism. Generally, the environmental friendliness and low cost of the material make it possible to be used for large-scale electric storage applications.
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