4.6 Article

Facile synthesis of dimeric BODIPY and its catalytic activity for sulfide oxidation under visible light

Journal

RSC ADVANCES
Volume 4, Issue 28, Pages 14786-14790

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra01501k

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Funding

  1. National Natural Science Foundation of China [21302014]
  2. Natural Science Foundation for Colleges and Universities of Jiangsu Province
  3. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology [BM2012110]

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An orthogonal dimeric BODIPY was easily prepared via condensation of 2,4-dimethylpyrrole and oxalyl dichloride, and was utilized as a visible-light-driven photocatalyst for the oxidation of sulfides. High catalytic efficiencies, and mild and green conditions are the major advantages of this protocol. Moreover, meso-carbalkoxylated BODIPYs could also be prepared using a similar one-pot condensation of 2,4-dimethylpyrrole, oxalyl dichloride and a series of alcohols.

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