4.6 Article

Interpenetrating network V2O5 nanosheets/carbon nanotubes nanocomposite for fast lithium storage

Journal

RSC ADVANCES
Volume 4, Issue 87, Pages 46624-46630

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra07937j

Keywords

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Funding

  1. International Science and Technology Cooperation Program of China [2013DFR50710]
  2. National Natural Science Foundation of China [51472189]
  3. Fundamental Research Funds for the Central Universities [20131049701001, 145101008]

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Rapid charge and discharge cathode materials for lithium-ion batteries have been commonly researched for the development of electrical mobility applications. Here, an interpenetrating network vanadium pentoxide (V2O5) nanosheets/carbon nanotubes (CNTs) nanocomposite was fabricated by a freeze-drying process. Field emission scanning electron microscopy and transmission electron microscopy tests indicated that the CNTs and V2O5 nanosheets form an interpenetrating network structure. X-ray diffraction and X-ray photoelectron spectroscopy analyses confirmed that the V2O5 nanosheets exhibit orthorhombic crystal structure and mixed element states in the nanocomposite. The electrochemical properties of the V2O5 nanosheets/CNTs nanocomposite were studied by cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge-discharge measurements. The results indicated that the V2O5 nanosheets/CNTs nanocomposite exhibits high specific capacity and good cycling stability. The initial specific capacity of the V2O5 nanosheets/CNTs nanocomposite is 130.7 mA h g(-1) for a current density up to 5.0 A g(-1) and remains at 100.1 mA h g(-1) after 100 cycles.

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