4.6 Article

Experimental assessment of physical upper limit for hydrogen storage capacity at 20 K in densified MIL-101 monoliths

Journal

RSC ADVANCES
Volume 4, Issue 6, Pages 2648-2651

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra46233a

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Funding

  1. International Max Planck Research School for Advanced Materials (IMPRS-AM)
  2. German Research Foundation DFG [SSP 1362]
  3. Romanian National Authority for Scientific Research, CNCS-UEFISCDI [PN-II-ID-PCE-2011-3-0350]
  4. COST Action

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The physical upper limit of hydrogen uptake for powder and compressed pellet MIL-101 has been experimentally investigated. Maximum uptake in pellets at 20 K achieves 9.6 wt% and 42 g L-1. Moreover, cryo-adsorption of hydrogen on pellets compared to liquid H-2 possesses a larger temperature window for operation without boil-off loss, which will be beneficial for industrial applications.

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