Journal
RSC ADVANCES
Volume 4, Issue 68, Pages 36053-36056Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra06802e
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Funding
- National Key Basic Research Program of China [2013CB933403]
- National Natural Science Foundation of China [91022014, 21073198]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB12010103]
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The hydrothermal reaction of 4,4'-dicarboxybiphenyl sulfone and dysprosium(III) nitrate in the presence of L-histidine yielded the first 2D -> 2D polyrotaxane lanthanide-organic framework, which possesses both polyrotaxane and polycatenane topology features. Magnetic investigations indicated that it is a field-induced single-molecule magnet with two-step magnetic relaxation processes.
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