Journal
RSC ADVANCES
Volume 4, Issue 54, Pages 28417-28420Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra04191g
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Funding
- DST, New Delhi
- CSIR, New Delhi
- UGC, New Delhi
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An electron deficient Cu(III)-corrole (B) has been identified as a highly selective colorimetric sensor for iodide. A one-electron redox couple between iodide and Cu(III)-corrole serves as the basis for selectivity. The proposed mechanism has been supported by UV-vis and F-19 NMR studies and further by unambiguous identification of Cu(II) species through EPR.
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