Journal
RSC ADVANCES
Volume 4, Issue 28, Pages 14475-14479Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra00655k
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- University of Santiago de Compostela
- Center for Research in Biological Chemistry and Molecular Materials (CIQUS)
- Ministry of Economy and Competitiveness
- Xunta de Galicia
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Aluminium trichloride catalyses the expeditious direct conversion of tetrahydropyranyl ethers to silyl ethers. This one-step transformation is chemoselective versus deprotection of the acetal and hydrosilylation of unsaturated carbon-carbon bonds, and can also be applied to linear acetals. A possible mechanism is tentatively proposed.
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