Journal
RSC ADVANCES
Volume 4, Issue 18, Pages 9275-9278Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra47062h
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Funding
- Department of Science and Technology (DST), New Delhi
- Council of Scientific and Industrial Research
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An experimentally simple one-pot reaction, affording 1,5-disubstituted 1H-1,2,3-triazoles in good to excellent yields by combining vinyl sulfones, sodium azide and alkyl bromides, -tosylates, -mesylates or aryl amines, -iodides is reported. The organic azides, generated in situ react with vinyl sulfones in a regioselective fashion in the absence of metal ions. Unlike many of the recently reported strategies, this method is capable of generating alkyl/alkyl, alkyl/aryl and aryl/aryl containing 1,5-disubstituted 1,2,3-triazoles under simple reaction conditions.
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