Journal
RSC ADVANCES
Volume 4, Issue 15, Pages 7579-7587Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra46462h
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Funding
- Russian Foundation for Basic Research [14-03-00237-a]
- Program for Basic Research of the Presidium of the Russian Academy of Sciences
- Ministry of Education and Science of the Russian Federation
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Reactions of mono- and bicyclic enol ethers with I-2-H2O2, I-2-(BuOOH)-O-t, and I-2-tetrahydropyranyl hydroperoxide systems have been studied. It was shown that the reaction pathway depends on the nature of peroxide and the ring size. The reaction of 2,3-dihydrofuran and 3,4-dihydro-2H-pyran with the I-2-hydroperoxide system affords iodoperoxides, alpha-iodolactones, and alpha-iodohemiacetals. Bicyclic enol ethers are transformed into vicinal iodoperoxides only in the reaction with the I-2-H2O2 system, whereas the reaction with I-2-ButOOH gives the hydroperoxidation product.
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