Journal
RSC ADVANCES
Volume 4, Issue 40, Pages 20649-20658Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra47652a
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Funding
- MacDiarmid Institute, the University of Canterbury
- Australian Synchrotron [AS121/SXRFI/4641a, AS121/SXR/4641b, AS122/SXR/5065]
- New Zealand Synchrotron Group
- Ministry for Business, Innovation and Employment New Zealand [C05X1207]
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Crystalline titanium dioxide was synthesised under mild conditions by the thermal degradation of peroxotitanic acid in the presence of a number of fluoride-containing surface modifying agents (NH4F, NH4BF4, NH4PF6, NBu4F, NBu4BF4, NBu4PF6). The resulting materials were characterised by PXRD, SEM, HRTEM, XPS and NEXAFS. Particle phase, size, and surface area were noticeably affected by the choice of surface modifying agent. Both the cation and anion comprising the modifying agent affect the surface Ti3+ population of the materials, with two apparent trends observed: F- > BF4- > PF6- and NBu4+ > NH4+. All materials displayed evidence of fluorine doping on their surfaces, although no evidence of bulk doping was observed.
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