Journal
RSC ADVANCES
Volume 4, Issue 9, Pages 4330-4333Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra46505e
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Funding
- National Natural Science Foundation of China [21272155, 21272147, 21072064]
- Innovation Program of Shanghai Municipal Education Commission [13YZ010]
- Research Fund for the Doctoral Program of Higher Education of China [20120061120117]
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Highly efficient complexation of per-ethylated pillar[7] arene towards 3,5-dimethyl-1-adamantyl ammonium cations is reported as the first example of pillar[7] arene-based molecular recognition. The binding affinity of the resulting inclusion complex is much higher than those for per-ethylated pillar[5,6] arenes with smaller cavities due to the strict size-fit effect.
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