4.6 Article

Postsynthetic modification of mixed-linker metal-organic frameworks for ethylene oligomerization

Journal

RSC ADVANCES
Volume 4, Issue 107, Pages 62343-62346

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra10605a

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Funding

  1. National Basic Research Program of China [2011CB606001]
  2. Fundamental Research Funds for the Central Universities [2012FZA4025, 2013FZA4023]

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A series of mixed-linker metal-organic frameworks (Zn4O(BDC)(x)-(ABDC)(3-x)) has been synthesized, and then transformed into nickel catalysts for ethylene oligomerization through quantitative postsynthetic modification. These complexes were more manageable, more stable, and more economic than analogues of IRMOF-3(x = 0) by post-modification.

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